Studies in Ion Solvation in Non-aqueous Solvents and Their Aqueous Mixtures: Part 15.1—Free Energies of Transfer of Cadmium Chloride from Water to 10-40 % (w/w) Methanol-Water Mixtures at 25°C; Dissociation of CdCD; Use of Dilute Cadmium Amalgam Electrodes. The Group II Cations

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dc.contributor.authorFeakins, D.
dc.contributor.authorWillmott, Alan S.
dc.contributor.authorWillmott, Ann R.
dc.date.accessioned2025-02-10T15:18:24Z
dc.date.available2025-02-10T15:18:24Z
dc.date.issued1973
dc.description.abstractThe cell Cd(Hg) | CdCl2 | AgCl—Ag has been used to obtain the standard molar free energies of transfer, AGt, of cadmium chloride from water to 10 %, 20 % and 40 % (w/w) mcthanol-water mixtures. Cadmium chloride is a weak electrolyte. This was allowed for in computing the standard e.m.f. values of the cell; dissociation constants of CdCl F were also determined. The behaviour of the Group II cations, Cd2+, Zn2+, Sr2+ and Ba2+, in the methanol-water system is discussed in terms of the “ acid-base ” theory and their “ hardness ” or “ softness ” as Lewis acids, and they are briefly compared with the univalent cations of Group I.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17467
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1)en_US
dc.subjectChemistryen_US
dc.subjectIon Solvationen_US
dc.subjectNon-aqueous Solventsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleStudies in Ion Solvation in Non-aqueous Solvents and Their Aqueous Mixtures: Part 15.1—Free Energies of Transfer of Cadmium Chloride from Water to 10-40 % (w/w) Methanol-Water Mixtures at 25°C; Dissociation of CdCD; Use of Dilute Cadmium Amalgam Electrodes. The Group II Cationsen_US
dc.typeArticleen_US

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