Adsorption and polymerization of acetylene on oxide surfaces. A Raman study

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dc.contributor.authorHeaviside, John
dc.contributor.authorHendra, Patrick J.
dc.contributor.authorTsai, Peter
dc.contributor.authorCooney, Ralph P.
dc.date.accessioned2025-11-18T09:16:30Z
dc.date.available2025-11-18T09:16:30Z
dc.date.issued1978
dc.description.abstractLaser Raman spectra have been recorded of adsorbed poly(acetylene) formed by the polymerization of acetylene on γ-alumina and zeolite KX. Spectral evidence indicates that on both γ-alumina and zeolite KX monomeric acetylene is physisorbed via its π electron system in a “side-on” orientation. The chain length of the polyene chains formed on γ-alumina appear to increase with increasing activation temperature. The line intensities in the Raman spectra of the coloured polyenes are significantly enhanced by resonance effects.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20082
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)en_US
dc.subjectChemistryen_US
dc.subjectRaman spectroscopyen_US
dc.subjectAcetylene polymerizationen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleAdsorption and polymerization of acetylene on oxide surfaces. A Raman studyen_US
dc.typeArticleen_US

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