Kinetics and Thermodynamics of the Proton-transfer Reactions of 2,4-Dinitrophenol with some Amine Bases in Chlorobenzene studied by a Microwave Temperature-jump Method

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dc.contributor.authorCaldin, Edward F.
dc.contributor.authorCrooks, John E.
dc.contributor.authorDonnell, Derek O’
dc.date.accessioned2025-02-12T05:08:48Z
dc.date.available2025-02-12T05:08:48Z
dc.date.issued1973
dc.description.abstractThe proton-transfer reactions of 2,4-dinitrophenol with trimethylamine, tri-n-octylamine, quinuclidine and triethylenediamine in chlorobenzene at 25CC have been studied. Equilibrium constants have been determined spectrophotometrically, and rate constants for some of the reactions have been determined by means of a microwave temperature-jump apparatus. The forward rate constants are one-tenth to one-hundredth of the value calculated for diffusion control. They do not correlate with the equilibrium constants, but appear to be related to steric factors.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17560
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6)en_US
dc.subjectChemistryen_US
dc.subjectProton-Transfer Reactionsen_US
dc.subjectKineticsen_US
dc.subjectThermodynamicsen_US
dc.subjectMicrowave Temperature-Jump Methoden_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleKinetics and Thermodynamics of the Proton-transfer Reactions of 2,4-Dinitrophenol with some Amine Bases in Chlorobenzene studied by a Microwave Temperature-jump Methoden_US
dc.typeArticleen_US

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