Transport in Aqueous Solutions of Group IIB Metal Salts at 298.15 K Part 5.—Irreversible Thermodynamic Parameters for Zinc Perchlorate and Verification of Onsager’s Reciprocal Relationships

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dc.contributor.authorAgnew, Andrew
dc.contributor.authorPaterson, Russell
dc.date.accessioned2025-11-20T11:09:25Z
dc.date.available2025-11-20T11:09:25Z
dc.date.issued1978
dc.description.abstractThe isothermal vectorial transport properties of zinc perchlorate have been measured over the concentration range 0.1–3.0 mol dm–3 at 298.15 K. Hittorf transport numbers were shown to agree with those measured earlier using concentration cells. Conductance and salt diffusion coefficients were also measured. These data were used to calculate mobility (Lik) and resistance (Rik) coefficients using irreversible thermodynamic theory. Analysis showed that the Onsager reciprocal relationships (O.R.R.) were obeyed.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20145
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)en_US
dc.subjectChemistryen_US
dc.subjectZinc perchlorateen_US
dc.subjectTransport propertiesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleTransport in Aqueous Solutions of Group IIB Metal Salts at 298.15 K Part 5.—Irreversible Thermodynamic Parameters for Zinc Perchlorate and Verification of Onsager’s Reciprocal Relationshipsen_US
dc.typeArticleen_US

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