Semiquinone Free Radicals and Oxygen: Pulse Radiolysis Study of One Electron Transfer Equilibria

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dc.contributor.authorPatel, Kantilal B.
dc.contributor.authorWillson, Robin L.
dc.date.accessioned2025-02-12T06:59:09Z
dc.date.available2025-02-12T06:59:09Z
dc.date.issued1973
dc.description.abstractThe absorption characteristics and acid dissociation constants of the semiquinone radicals of several methyl derivatives of benzoquinone and naphthoquinone have been determined by pulse radiolysis. Absolute rate constants for electron transfer from the superoxide-ion O–2 to mono- and di-methyl benzoquinones have been determined. In the case of duroquinone, evidence has been obtained for the occurrence of the equilibrium reaction: O–2+ duroquinone ⇌ O2+ durosemiquinone with Kc= 2.3 ± 0.2 × 10–2.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/17596
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (4)en_US
dc.subjectChemistryen_US
dc.subjectPulse Radiolysisen_US
dc.subjectElectron Transfer Equilibriaen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleSemiquinone Free Radicals and Oxygen: Pulse Radiolysis Study of One Electron Transfer Equilibriaen_US
dc.typeArticleen_US

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