Pulse Radiolysis Study of the Reaction of Solvated Electrons with Sulphur Hexafluoride in Methanolic Solution
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Date
1977
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Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12)
Abstract
The rate constant for the reaction of e–s with SF6 in deaerated methanolic solution has been determined to be k3=(1.88 ± 0.06)× 1010 dm3 mol–1 s–1. The product of this reaction, ·SF5, has an absorption spectrum with a maximum at 300 nm with ε= 1300 dm3 mol–1 cm–1 and decays by mixed first- and second-order kinetics.
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Keywords
Chemistry, Radiation chemistry, Electron transfer reactions, Journal of the Chemical Society : Faraday Transaction - I