Capillary Phenomena Part 5.—Equilibrium and Stability of Solid Cones in Fluid/Fluid Interfaces
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Date
1977
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Publisher
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12)
Abstract
Conditions are given for the equilibrium paths followed by cones (axis vertical) in interfaces between two fluids, when raised and lowered by an applied force: using a tensiometer or a rigid (damped) device. Circumstances are described under which these conditions are stable. The instability and detachment of cones with contact angle θ < χ+ 90°, where χ is the half-angle at the apex of the cone generating triangle, at a maximum in the displacement of the cone apex gives a method of determining the fluid/fluid interfacial tension. Conditions under which cones can float unaided are also given. Comparison is made with the behaviour of other capillary systems.
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Keywords
Chemistry, Capillary phenomena, Interfacial equilibrium, Journal of the Chemical Society : Faraday Transaction - I