Reaction of Oxygen Atoms with Carbonyl Compounds: Part 2.—Acetaldehyde

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dc.contributor.authorMack, G. P. R.
dc.contributor.authorThrush, B. A.
dc.date.accessioned2025-02-15T06:57:03Z
dc.date.available2025-02-15T06:57:03Z
dc.date.issued1974
dc.description.abstractThe reaction of excess atomic oxygen with acetaldehyde in a discharge-flow system has been studied at temperatures between 195 and 573 K. Kinetic studies and product analyses establish the mechanism to be O + CH3CHO → CH3CO + OH (1), O + OH → O2+ H (2), O + CH3CO → CH3+ CO2(9), O + CH3→ H2CO + H (7) followed by reaction between oxygen atoms and formaldehyde. At 573 K, the reduction of the carbon dioxide yield on increasing the pressure from 1 to 10 Torr is caused by unimolecular decomposition of acetyl radicals. At 300 K, k1=(2.88 ± 0.3)× 1011 cm3 mol–1 s–1.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17779
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)en_US
dc.subjectChemistryen_US
dc.subjectOxygen Atomsen_US
dc.subjectCarbonyl Compoundsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleReaction of Oxygen Atoms with Carbonyl Compounds: Part 2.—Acetaldehydeen_US
dc.typeArticleen_US

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