Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate: Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate

Simple item page
dc.contributor.authorLaskar, Inamur Rahaman
dc.date.accessioned2021-10-27T04:27:03Z
dc.date.available2021-10-27T04:27:03Z
dc.date.issued1998
dc.description.abstractThe blue complex cis-[Ni(dipren)2(NO3)](NO3) 1 and the greenish blue cis-[Ni(dipren)2(H2O2](NO3)2 · 2H2O2 (dpren/dpren = dipropyl/diisopropylethane-1,2-diamine) have been synthesized. Complex 2 upon heating loses four water molecules in a single step and undergoes melting accompanied with colour change, greenish blue to deep green, 2a. Configuration of the complexes 1,2 and 2a have been proposed to be cis-octahedral on the basis of magnetic, IR and electronic spectroscopic studies and confirmed in case of complex 1 by X-ray single crystal structure analysis. The role of steric factor of the alkyl groups on the selectivity of coordinating mode of nitrate ion is studied.en_US
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0277538797002830
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3155
dc.language.isoenen_US
dc.publisherElsieveren_US
dc.subjectChemistryen_US
dc.subjectN,N′-dipropylethane-1,2-diamineen_US
dc.subjectCis-octahedral geometry of nickel(II) diamine complexen_US
dc.subjectThermochronismen_US
dc.titleSyntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate: Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrateen_US
dc.typeArticleen_US

Files

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Department of Chemistry