Absolute Rate of the Reaction of C1(2P) with Molecular Hydrogen from 200-500 K

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dc.contributor.authorLee, Jai H.
dc.contributor.authorMichael, Joe V
dc.contributor.authorPayne, Walter A.
dc.contributor.authorStiee, Louis J.
dc.date.accessioned2025-12-11T10:08:22Z
dc.date.available2025-12-11T10:08:22Z
dc.date.issued1977
dc.description.abstractRate constants for the reaction of atomic chlorine with hydrogen have been measured from 200–500 K using the flash photolysis–resonance fluorescence technique. The rate constants obey the Arrhenius equation k=(2.66 ± 0.42)× 10–11 exp (–2230 ± 60/T) cm3 molecule–1 s–1. The results are compared with previous work and are discussed with particular reference to the equilibrium constant for the reaction and to relative rate data for chlorine atom reactions. Theoretical calculations, using the BEBO method with tunnelling, give excellent agreement with experiment.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20363
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10)en_US
dc.subjectChemistryen_US
dc.subjectMolecular hydrogenen_US
dc.subjectChemical reaction dynamicsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleAbsolute Rate of the Reaction of C1(2P) with Molecular Hydrogen from 200-500 Ken_US
dc.typeThesisen_US

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