Spectrophotometric Investigations of Aqueous Solutions at Elevated Temperatures

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dc.contributor.authorAlexander, Roger D.
dc.contributor.authorBuisson, David H.
dc.contributor.authorDudeney, A. William L.
dc.contributor.authorIrving, Roger J.
dc.date.accessioned2025-03-19T10:59:06Z
dc.date.available2025-03-19T10:59:06Z
dc.date.issued1978
dc.description.abstractThe overall stability constants (β3) of the tris complexes of 1,10-phenanthroline, 5-nitro-1,10 phenanthroline and 2,2′-bipyridyl with iron (II) have been determined at various temperatures between 298 and 433 K by a new spectrophotometric method. The value of β3 for all three complexes decreases regularly with increasing temperature as expected. Plots of log10β3 against 1/T have been used to determine average values of the thermodynamic functions (enthalpy and entropy) of the formation reaction in aqueous solution over the experimental temperature range.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/18423
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05)en_US
dc.subjectChemistryen_US
dc.subjectSpectrophotometric investigationsen_US
dc.subjectaqueous solutionsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleSpectrophotometric Investigations of Aqueous Solutions at Elevated Temperaturesen_US
dc.typeArticleen_US

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