Reactions of n-butenes on palladium films. Evidence for π-allylic species

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dc.contributor.authorLedoux, Marc J.
dc.contributor.authorGault, François G.
dc.contributor.authorBouchy, Alain
dc.contributor.authorRoussy, Georges
dc.date.accessioned2025-11-18T10:59:01Z
dc.date.available2025-11-18T10:59:01Z
dc.date.issued1978
dc.description.abstractThe contact reactions of all three n-butenes have been investigated on palladium films in the presence of perdeuteropropene or deuterium, using jointly mass spectrometry and microwave spectroscopy. Conclusive evidence has been found for an allylic mechanism in exchange and double-bond migration. Part of the exchanged molecules result from dissociative vinylic-type adsorption and isomerization also takes place according to an associative Horiuti–Polanyi mechanism or by direct processes without deuterium incorporation. A proposal was made which correlates the various reaction mechanisms with various types of surface metal atoms, each having a different coordination number.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20093
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)en_US
dc.subjectChemistryen_US
dc.subjectPalladium filmsen_US
dc.subjectn-Butenesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleReactions of n-butenes on palladium films. Evidence for π-allylic speciesen_US
dc.typeArticleen_US

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