Catalyzed Thermal Decomposition of Organic Acids: Part 2.—Catalyzed Decomposition of Cyclopentane- and Cycloheptane-carboxylic Acids by Hydrogen Bromide

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dc.contributor.authorAhonkhai, S. I.
dc.contributor.authorEmovon, E. U.
dc.date.accessioned2025-02-11T07:29:25Z
dc.date.available2025-02-11T07:29:25Z
dc.date.issued1973
dc.description.abstractCyclopcntanc- and cycloheptane-carboxylic acids decompose by a molecular mechanism into carbon monoxide, water and the corresponding alkene on catalysis by HBr in a seasoned Pyrex vessel. The decomposition is homogeneous and first order in acid and catalyst, HBr. The second order rate constants, expressed by the Arrhenius equations are: k2 = 1012.17e-29 550/RTcm3mol-1 s-1 for cycloheptanecarboxylic acid and k2 = 1013.49e-34 590/RTcm3mol-1 S-1 for cyclopentanecarboxylic acid over the temperature range 369.0-434.0°C (R in cal mol"1).en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17509
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1)en_US
dc.subjectChemistryen_US
dc.subjectThermal Decompositionen_US
dc.subjectOrganic Acidsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleCatalyzed Thermal Decomposition of Organic Acids: Part 2.—Catalyzed Decomposition of Cyclopentane- and Cycloheptane-carboxylic Acids by Hydrogen Bromideen_US
dc.typeArticleen_US

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