Free Radical Addition to Olefins: Part 10.—Addition of Dibromofluoromethyl Radicals to Fluoroethylenes

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dc.contributor.authorSloan, John P.
dc.contributor.authorTedder, John M.
dc.contributor.authorWalton, John C.
dc.date.accessioned2025-02-13T06:26:17Z
dc.date.available2025-02-13T06:26:17Z
dc.date.issued1973
dc.description.abstractThe gas phase photochemical addition of tribromofluoromethane to a series of fluoro-olefins has been studied over a range of temperatures. The products included those from addition of dibromofluoromethyl radicals to the olefins as well as cyclopropanes from addition of bromofluorocarbene. The mechanism of the reaction is discussed, and Arrhenius parameters for the addition of dibromofluoromethyl radicals are derived from competitive experiments with each olefin and ethylene. [graphic omitted] Activation energies, relative to ethylene, in kcal mol–1, A-factors in l. mol–1 s–1(1 cal = 4.184 J).en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17670
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6)en_US
dc.subjectChemistryen_US
dc.subjectFree Radical Additionen_US
dc.subjectOlefinsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleFree Radical Addition to Olefins: Part 10.—Addition of Dibromofluoromethyl Radicals to Fluoroethylenesen_US
dc.typeArticleen_US

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