Electrochemical Oxidative Addition of Nucleophiles on 2-Arylindoles: Synthesis of C2-Heteroquaternary Indolin-3-ones

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dc.contributor.authorKumar, Indresh
dc.date.accessioned2024-09-12T04:19:25Z
dc.date.available2024-09-12T04:19:25Z
dc.date.issued2022-11
dc.description.abstractAn electrochemical method has been developed to synthesize 2,2-disubstituted indolin-3-ones under mild conditions. A series of nucleophiles have been added to the 2-arylindole-3-ones, generated in situ under metal-free electrochemical oxidative dearomatization of 2-arylindoles, to afford 2,2-disubstituted 3-carbonyl indoles with heteroquaternary centers in 57–79% yields.en_US
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/acs.joc.2c01734
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15544
dc.language.isoenen_US
dc.publisherACSen_US
dc.subjectChemistryen_US
dc.subjectElectrodesen_US
dc.subjectFossil fuelsen_US
dc.subjectIndolesen_US
dc.subjectSubstitution reactionsen_US
dc.titleElectrochemical Oxidative Addition of Nucleophiles on 2-Arylindoles: Synthesis of C2-Heteroquaternary Indolin-3-onesen_US
dc.typeArticleen_US

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