Product crystallite size–reaction rate relationship in M(OH)2–MO decomposition. Structural transformation mechanism

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dc.contributor.authorNiepce, Jean-Claude
dc.contributor.authorWatelle, Ginette
dc.contributor.authorBrett, Norman H.
dc.date.accessioned2025-04-12T04:44:52Z
dc.date.available2025-04-12T04:44:52Z
dc.date.issued1978
dc.description.abstractTwo mechanisms were proposed to explain the decomposition reaction of brucite: the homogeneous and the inhomogeneous mechanisms. These two mechanisms, on the one hand, and the main structural transformation modes, on the other, are reviewed and discussed in connection with an important new result. When no sintering occurs the oxide crystallite size is independent of temperature, i.e. it is independent of the overall reaction rate. This result excludes a diffusion process and is in agreement with the homogeneous mechanism. It is shown that the structural transformation associated with this reaction exhibits the most important morphological and structural features of a shear transformation.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/18652
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06)en_US
dc.subjectChemistryen_US
dc.subjectCrystallite sizeen_US
dc.subjectReaction rateen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleProduct crystallite size–reaction rate relationship in M(OH)2–MO decomposition. Structural transformation mechanismen_US
dc.typeArticleen_US

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