Modeling of Ethylene Polymerization with Zirconocene Catalyst and Estimation of Kinetic Parameters using Differential Evolution Algorithm

dc.contributor.authorSharma, A. K.
dc.date.accessioned2021-10-05T11:51:34Z
dc.date.available2021-10-05T11:51:34Z
dc.date.issued2012
dc.description.abstractZirconocene catalyzed olefin polymers have experienced radical attention owing to their unmatched properties and wide applications. Metallocene polyethylene (mPE) shows a narrow molecular weight distribution and a very homogeneous copolymer distribution. Kinetic model of the gas phase ethylene polymerization with silica supported (dimethylsilylene)bis(η5–inden–1–ylidene)zirconium dichloride catalyst and MAO as cocatalyst is proposed. Polymer molecular properties, viz. number average molecular weight ( ), weight average molecular weight ( ), and polydispersity index (PDI) are calculated using the method of moments. Kinetic parameters have been estimated using differential evolution (DE) approach of optimization.en_US
dc.identifier.urihttps://www.proquest.com/docview/1726672139
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2540
dc.language.isoenen_US
dc.publisherIJCMen_US
dc.subjectChemical Engineeringen_US
dc.subjectZirconoceneen_US
dc.subjectMAOen_US
dc.subjectEthyleneen_US
dc.titleModeling of Ethylene Polymerization with Zirconocene Catalyst and Estimation of Kinetic Parameters using Differential Evolution Algorithmen_US
dc.typeArticleen_US

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