Nuclear Magnetic Relaxation Studies of Preferential Solvation in Electrolyte Solutions

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dc.contributor.authorCapparelli, Alberto L.
dc.contributor.authorGill, Dip S.
dc.contributor.authorHertz, H. Gerhard
dc.contributor.authorTutsch, Rüdiger
dc.contributor.authorWeingärtner, Hermann
dc.date.accessioned2025-04-28T09:06:42Z
dc.date.available2025-04-28T09:06:42Z
dc.date.issued1978
dc.description.abstractFormulae are derived which describe the increase in the total proton magnetic relaxation rate relative to the intramolecular relaxation rate in a solvent mixture when solvent molecules of one kind are enriched in the solvation sphere of a dissolved ion. Experimental nuclear magnetic relaxation results regarding the application of these formulae for solutions of Mg(ClO4)2, KI and RbI in water + methanol mixtures are reported. It is shown that preferential solvation effects are present in these systems, they are ascribed to preferential hydration of the cations.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18811
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07)en_US
dc.subjectChemistryen_US
dc.subjectNuclear magnetic relaxationen_US
dc.subjectSolvent–solvent interactionsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleNuclear Magnetic Relaxation Studies of Preferential Solvation in Electrolyte Solutionsen_US
dc.typeArticleen_US

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