Sodium-23 quadrupole splittings in lyotropic liquid crystals. Relationship to electrical double layer theory and estimates of double layer dimensions

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dc.contributor.authorTiddy, Gordon J. T.
dc.contributor.authorLindblom, Göran
dc.contributor.authorLindman, Björn
dc.date.accessioned2025-04-09T09:58:27Z
dc.date.available2025-04-09T09:58:27Z
dc.date.issued1978
dc.description.abstractIt is proposed that the magnitudes of n.m.r. quadrupole splittings of ions in lyotropic liquid crystals are related to the fractional concentration of the ions in the bound water at the lipid/water interface. Ions in the remaining water have zero splittings. Sodium-23 splittings are reported for cationic and anionic amphiphile systems at different salt concentrations and strongly support the proposed explanation. In favourable cases it is possible to obtain measurements of the double layer thickness. It was not possible to observe any displacement of sodium ions by magnesium or lanthanum ions in the concentration ranges studied.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18595
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05)en_US
dc.subjectChemistryen_US
dc.subjectLyotropic liquid crystalsen_US
dc.subjectElectrical Double Layer Theoryen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleSodium-23 quadrupole splittings in lyotropic liquid crystals. Relationship to electrical double layer theory and estimates of double layer dimensionsen_US
dc.typeArticleen_US

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