Self-reactions of Isopropylperoxy Radicals in the Gas Phase
| dc.contributor.author | Kirsch, Leslie J. | |
| dc.contributor.author | Parkes, David A. | |
| dc.contributor.author | Waddington, David J. | |
| dc.contributor.author | Woolley, Allan | |
| dc.date.accessioned | 2025-05-09T09:23:18Z | |
| dc.date.available | 2025-05-09T09:23:18Z | |
| dc.date.issued | 1978 | |
| dc.description.abstract | The photo-oxidation of 2,2′-azopropane has been studied in order to determine the overall rate constant for the second-order removal of isopropylperoxy radicals. Arrhenius parameters of log10(Aobs/dm3 mol–1 s–1)= 9.15 ± 0.03 and Eobs= 18.65 ± 0.50 kJ mol–1 have been determined over a temperature range 300–373 K. These values are compared with those obtained for the self-reactions of primary and tertiary alkylperoxyradicals, and the corresponding reactions in solution. | en_US |
| dc.identifier.uri | https://dspace.bits-pilani.ac.in/handle/123456789/18899 | |
| dc.language.iso | en | en_US |
| dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12) | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Isopropylperoxy radical | en_US |
| dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
| dc.title | Self-reactions of Isopropylperoxy Radicals in the Gas Phase | en_US |
| dc.type | Article | en_US |