Kinetics of the Reaction of Hydrogen Atoms with 1,I-Difluoroethylene

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dc.contributor.authorTeng, L.
dc.contributor.authorJones, W. E.
dc.date.accessioned2025-02-11T07:32:05Z
dc.date.available2025-02-11T07:32:05Z
dc.date.issued1973
dc.description.abstractHydrogen atoms generated in a Wood-Bonhoeflcr discharge were reacted with 1,1-difluoroethylene. The products of the reaction were: HF, C2H4, C2H6, C2H2, CH4, C3H6, n-C4H10, ( 3H8 and C2H3F. With the exception of HF, n-C4H10 and C3H8, al! were quantitatively studied over the temperature range 303-603 K. The kinetics and mechanism of the H atom4-CF2CH2 reaction have been studied in detail. The rate constants have been calculated for each step of the mechanism for three temperatures allowing determination of activation energies. The calculation of the rate constants and testing of the mechanism were accomplished by numerical integration of the simultaneous differential equations for each species involved in the reaction.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17510
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1)en_US
dc.subjectChemistryen_US
dc.subjectHydrogen Atomsen_US
dc.subjectDifluoroethyleneen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleKinetics of the Reaction of Hydrogen Atoms with 1,I-Difluoroethyleneen_US
dc.typeArticleen_US

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