Kinetics of Methylene Addition to cis- and r/w?s-But-2-ene: Further Evidence for the Energy Separation between Triplet and Singlet Methylene

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dc.contributor.authorFrey, Henry M
dc.contributor.authorKennedy, Gordon J.
dc.date.accessioned2025-04-07T06:31:08Z
dc.date.available2025-04-07T06:31:08Z
dc.date.issued1977
dc.description.abstractThe reactions of triplet and singlet methylene with cis- and trans-but-2-ene have been studied over the temperature range 350–473 K. The results yield a value of (36.5 ± 3.2) kJ mol–1 for the energy separation between singlet and triplet methylene, and provide further confirmation of the assumption that singlet methylene reactions with hydrocarbons proceed with activation energies close to zero. Previous evidence for the similar reactivities of triplet methylene and the methyl radical receives additional support.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18558
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1)en_US
dc.subjectChemistryen_US
dc.subjectKineticsen_US
dc.subjectMethyleneen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleKinetics of Methylene Addition to cis- and r/w?s-But-2-ene: Further Evidence for the Energy Separation between Triplet and Singlet Methyleneen_US
dc.typeArticleen_US

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