Solubility of helium and hydrogen in some water + alcohol systems

Simple item page
dc.contributor.authorCargill, Robert W.
dc.date.accessioned2025-04-11T05:56:32Z
dc.date.available2025-04-11T05:56:32Z
dc.date.issued1978
dc.description.abstractThe solubility of helium and of hydrogen in water + ethanol and in water + t-butanol mixtures has been measured over the whole range of mixture compositions and at several temperatures between 4 and 62°C. The thermodynamic functions ΔG⊖, ΔH⊖, ΔS⊖ and ΔC⊖p were calculated for the solution process, assuming ideal behaviour. The dependence of these functions on alcohol concentration and on the gaseous solute provides further evidence that the effect of these substances on the structure of water is related to the size of their molecules. A detailed analysis supports the “flickering-cluster” model of water structure, and provides some indication of relative cluster size and its temperature dependence.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18629
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06)en_US
dc.subjectChemistryen_US
dc.subjectWater–alcohol mixturesen_US
dc.subjectSolubility of heliumen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.subjectSolubility of hydrogenen_US
dc.titleSolubility of helium and hydrogen in some water + alcohol systemsen_US
dc.typeArticleen_US

Files

Collections

Journal Articles (before-1995)