Redox Behaviour of Transition Metal Ions in Zeolites Part 6.—Reversibility of the Reduction Reaction in Silver Zeolites

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dc.contributor.authorJacobs, Peter A
dc.contributor.authorUytterhoeven, Jan B
dc.contributor.authorBeyer, Hermann K
dc.date.accessioned2025-12-29T05:23:03Z
dc.date.available2025-12-29T05:23:03Z
dc.date.issued1977
dc.description.abstractIn this paper is shown that hydrogen is formed by oxidative thermal desorption from Y-zeolite or mordenite containing highly dispersed silver metal in the cages. Upon thermal degassing above 573 K, hydrogen is desorbed from previously reduced Ag zeolites. At the same time, silver metal is reoxidized and located as Ag+ ions in lattice positions and lattice hydroxyl groups disappear. The following methods are used to characterize the system; isothermal and temperature programmed consumption or desorption of hydrogen in a volumetric system; i.r. spectroscopy of the hydroxyl region; i.r. spectroscopy of adsorbed carbon monoxide and pyridine; X-ray diffraction of Ag0 crystallites.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/20461
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11)en_US
dc.subjectChemistryen_US
dc.subjectRedox behavioren_US
dc.subjectZeolitesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleRedox Behaviour of Transition Metal Ions in Zeolites Part 6.—Reversibility of the Reduction Reaction in Silver Zeolitesen_US
dc.typeThesisen_US

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