Oxidation of Ferrous Ions by Hydroxyl Radicals

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dc.contributor.authorJayson, G. G.
dc.contributor.authorParsons, B. J.
dc.contributor.authorSwallow, A. J.
dc.date.accessioned2025-02-03T06:54:54Z
dc.date.available2025-02-03T06:54:54Z
dc.date.issued1972
dc.description.abstractHydroxyl radicals have been found by pulse radiolysis to oxidize hydrated ferrous to ferric ions with a rate constant of (2.3 ± 0.2)× 108 M–1 s–1. The corresponding reaction of OD radicals in D2O solution has a rate constant of (9.4 ± 0.8)× 107 M–1 s–1. OD radicals oxidize ferrocyanide in D2O solution with (9.7 ± 1.0)× 109 M–1 s–1. The mechanism of the oxidation of ferrous ions is though to consist of simple electron transfer, and the difference in rate between H2O and D2O solution is attributed to differences between free energies of hydration in the two solvents.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17042
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11)en_US
dc.subjectChemistryen_US
dc.subjectOxidationen_US
dc.subjectFerrous Ionsen_US
dc.subjectHydroxyl Radicalsen_US
dc.subjectRedox Reactionsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleOxidation of Ferrous Ions by Hydroxyl Radicalsen_US
dc.typeArticleen_US

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