Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films

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dc.contributor.authorArroyo, Antonio Cortes
dc.contributor.authorKemball, C.
dc.date.accessioned2025-02-08T02:46:48Z
dc.date.available2025-02-08T02:46:48Z
dc.date.issued1972
dc.description.abstractThe exchange of n-butane with deuterium is catalyzed by tungsten films at temperatures below 250 K; the reaction involves mainly simple exchange with no evidence of self-poisoning. The adsorption of butane on tungsten at temperatures from 273 to 423 K gives strongly adsorbed hydrocarbon species which reduce the rate of the subsequent exchange at 273 K by factors of from 10 to 2000, the effect increasing with the adsorption temperature. Only a fraction of these adsorbed species is easily rehydrogenated. Some results for comparison arc obtained with adsorbed but-l-ene, neopentane or methane.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/17388
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6)en_US
dc.subjectChemistryen_US
dc.subjectAdsorbed Hydrocarbonen_US
dc.subjectCatalytic Exchangeen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleEffect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Filmsen_US
dc.typeArticleen_US

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