Nuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solvents

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dc.contributor.authorCovington, Arthur K.
dc.contributor.authorLantzke, Ian R.
dc.contributor.authorThain, Jennifer M.
dc.date.accessioned2025-03-07T10:40:08Z
dc.date.available2025-03-07T10:40:08Z
dc.date.issued1974
dc.description.abstractStudies of 7Li and 133Cs ion n.m.r. chemical shifts in dimethyl sulphoxide (DMSO)+ water mixtures, have been interpreted in terms of a series of competitive equilibria in which the solvation number of the ions for DMSO is half that for water. It is concluded that nitrate ions are preferentially solvated by DMSO and Li+ by water. The treatment has also been applied to 133Cs shift data for sulpholan and water mixtures, and it is concluded that caesium ions are solvated by the organic component.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18202
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10)en_US
dc.subjectChemistryen_US
dc.subjectNuclear Magnetic Resonance (NMR) Spectroscopyen_US
dc.subjectPreferential Solvationen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleNuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solventsen_US
dc.typeArticleen_US

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