Equilibria in the Fe2(SO4)3/Fe2O3/SO3 System
| dc.contributor.author | Halstead, W. David | |
| dc.contributor.author | Laxton, James W. | |
| dc.date.accessioned | 2025-02-14T06:18:32Z | |
| dc.date.available | 2025-02-14T06:18:32Z | |
| dc.date.issued | 1974 | |
| dc.description.abstract | The pressures of SO3 which exist in equilibrium with ferric sulphate have been measured in the temperature range 740 to 975 K by static and dynamic techniques. The overall equilibrium may be described by the two equations Fe2(SO4)3⇌Fe2O3+ 3SO3, 2SO3⇌2SO2+ O2 The equilibrium SO3 pressures above partially sulphated samples prepared from α-Fe2O3 follow the equation log10(PSO3/N m–2)= 14.18 ± 1.39 –(0.95 ± 0.11)K//T× 104 while for partially sulphated samples prepard from γ-Fe2O3 the equation log10(PSO3/N m–2)= 13.17 ± 1.10 –(0.91 ± 0.09)K//T× 104 holds. The latter equation is in good agreement with previously published equilibrium pressure data. | en_US |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17712 | |
| dc.language.iso | en | en_US |
| dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Equilibria | en_US |
| dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
| dc.title | Equilibria in the Fe2(SO4)3/Fe2O3/SO3 System | en_US |
| dc.type | Article | en_US |