Thermal Decomposition of Ethyl, Isopropyl and t-Butyl Fluorides in the Gas Phase

Simple item page
dc.contributor.authorDastoor, P. N.
dc.contributor.authorEmovon, E. U.
dc.date.accessioned2025-02-03T11:56:03Z
dc.date.available2025-02-03T11:56:03Z
dc.date.issued1972
dc.description.abstractEthyl, isopropyl and t-butyl fluorides decompose in a flow system into hydrogen fluoride and the corresponding olefin by a predominantly molecular mechanism. The first order rate constants are given by the Arrhenius equations: ethyl fluoride (520–600°C) : k/s–1= 1012.16±0.04exp–59 200±2000/RT, isopropyl fluoride(445–522°C) : k/s–1= 1011.83±0.02 exp–53 900±800/RT, t-butyl fluoride (329–370°C) : k/s–1= 1013.96±0.01 exp–50 400±900/RT.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17109
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11)en_US
dc.subjectChemistryen_US
dc.subjectThermal Decompositionen_US
dc.subjectAlkyl Fluoridesen_US
dc.subjectGas-Phase Reactionsen_US
dc.subjectReaction Kineticsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleThermal Decomposition of Ethyl, Isopropyl and t-Butyl Fluorides in the Gas Phaseen_US
dc.typeArticleen_US

Files

Collections

Journal Articles (before-1995)