Thermodynamic Studies of Hydrochloric Acid in Propan-2-ol from Electromotive Force Measurements between 5 and 45°C

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dc.contributor.authorRoy, Rabindra N.
dc.contributor.authorVernon, William
dc.contributor.authorBothwell, Alfred L. M.
dc.date.accessioned2025-02-03T06:41:58Z
dc.date.available2025-02-03T06:41:58Z
dc.date.issued1972
dc.description.abstractThe e.m.f. of the cell Pt, H2(g, 1 atm)| HCl(m), propan-2-ol | AgCl, Ag at 5°C intervals from 5 to 45°C for hydrochloric acid solutions in the range 0.005 to 0.1 mol kg–1 has been used to calculate (a) the standard e.m.f. of the cell at each temperature, (b) the mean molal activity coefficients of HCl at 25°C, (c) the primary medium effet, and (d) the thermodynamic transfer quantities, ΔG°t, ΔH°t, ΔS°t, and ΔC°pt for the transfer of HCl from water to propan-2-ol. The significance of the evaluated thermodynamic functions for the transfer process has been discussed in relation to the acid-base strength, as well as the structural features of the solvents (water and propan-2-ol).en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/17036
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11)en_US
dc.subjectChemistryen_US
dc.subjectThermodynamic Studiesen_US
dc.subjectHydrochloric Aciden_US
dc.subjectPropan-2-olen_US
dc.subjectElectromotive Force Measurementsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleThermodynamic Studies of Hydrochloric Acid in Propan-2-ol from Electromotive Force Measurements between 5 and 45°Cen_US
dc.typeArticleen_US

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