Reactions of Alkyl Radicals with Nitrogen Trifluoride

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dc.contributor.authorCadman, Philip
dc.contributor.authorInel, Yuksel
dc.contributor.authorTrotman-Dickenson, Aubrey F.
dc.date.accessioned2025-05-09T09:36:03Z
dc.date.available2025-05-09T09:36:03Z
dc.date.issued1978
dc.description.abstractPhotolysis of mixtures of nitrogen trifluoride with the appropriate ketones (in the temperature range 303–486 K) has enabled the reactions of CH3, CF3, C2H5, i-C3H7 and t-C4H9 radicals with nitrogen trifluoride to be studied. With the smaller radicals only the abstraction of difluoroamino radicals is important, but with i-C3H7 and t-butyl both difluoroamino and fluorine abstraction occur. The Arrhenius parameters are given. The disproportionation—combination ratio for methyl and t-butyl radicals was found to be 0.83 ± 0.02.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18900
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)en_US
dc.subjectChemistryen_US
dc.subjectNitrogen trifluorideen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleReactions of Alkyl Radicals with Nitrogen Trifluorideen_US
dc.typeArticleen_US

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