Abstraction of Chlorine Atoms from Alkyl Chlorides by the Trimethylsilyl Radical

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dc.contributor.authorCadman, P.
dc.contributor.authorTilsley, G. M.
dc.contributor.authorDickenson, A. F. Trotman
dc.date.accessioned2025-02-13T06:08:22Z
dc.date.available2025-02-13T06:08:22Z
dc.date.issued1973
dc.description.abstractThe relative rates of chlorine atom abstraction from alkyl chlorides by the trimethylsilyl radical have been studied by a competitive technique between 400 and 580 K in the gas phase. These results have been put on an absolute basis by comparing the rate of abstraction of chlorine from ethyl chloride by trimethylsilyl radicals with their rate of combination to hexamethyldisilane. Using the known rate of combination of trimethylsilyl radicals, the following Arrhenius parameters for chlorine abstraction were obtained: [graphic omitted] The results of the chlorine abstractions by the trimethylsilyl radicals are compared with those for sodium atoms and for trichlorosilyl radicals.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17664
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5)en_US
dc.subjectChemistryen_US
dc.subjectAbstractionen_US
dc.subjectChlorine Atomsen_US
dc.subjectAlkyl Chloridesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleAbstraction of Chlorine Atoms from Alkyl Chlorides by the Trimethylsilyl Radicalen_US
dc.typeArticleen_US

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