Transport in aqueous solutions of group IIB metal salts at 298.15 K. Part 6.—Irreversible thermodynamic parameters for zinc chloride and verification of Onsager's reciprocal relationships

Simple item page
dc.contributor.authorAgnew, Andrew
dc.contributor.authorPaterson, Russell
dc.date.accessioned2025-11-20T11:12:33Z
dc.date.available2025-11-20T11:12:33Z
dc.date.issued1978
dc.description.abstractThe isothermal vectorial transport properties of zinc chloride (conductance, transport number and salt diffusion coefficients) have been measured over the concentration range 0.1–3.5 mol dm–3 at 298.15 K. These data have been used to calculate mobility (Lik) and resistance (Rik) coefficients, using irreversible thermodynamic theory. Hittorf and concentration cell estimates of transport number have been used to verify the Onsager reciprocal relationships. The effects of self complexing in zinc chloride are illustrated by comparison with zinc perchlorate and other group IIB metal halides for which data are available.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20146
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)en_US
dc.subjectChemistryen_US
dc.subjectZinc chlorideen_US
dc.subjectIrreversible thermodynamicsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleTransport in aqueous solutions of group IIB metal salts at 298.15 K. Part 6.—Irreversible thermodynamic parameters for zinc chloride and verification of Onsager's reciprocal relationshipsen_US
dc.typeArticleen_US

Files

Collections

Journal Articles (before-1995)