Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study
| dc.contributor.author | Roy, Ram Kinkar | |
| dc.date.accessioned | 2021-10-12T11:32:39Z | |
| dc.date.available | 2021-10-12T11:32:39Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | An azide (–N3) group attached at the -ortho carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol formed a diradical-containing Co(II) complex via inter-ligand azo (N[double bond, length as m-dash]N) bond formation. Metal-to-ligand (azo), dπ-to-pπ* back donation stabilized the metal in its lower oxidation state. | en_US |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2015/DT/C4DT03214D | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2725 | |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Inter-ligand azo | en_US |
| dc.title | Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study | en_US |
| dc.type | Article | en_US |
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