Electron Spin Resonance Study of the Reaction of Hydrogen Atoms with Hydrogen Sulphide

Simple item page
dc.contributor.authorBradley, John N.
dc.contributor.authorTrueman, Susan P.
dc.contributor.authorWhytock, David A.
dc.contributor.authorZaleski, Thomas A.
dc.date.accessioned2025-02-11T07:21:37Z
dc.date.available2025-02-11T07:21:37Z
dc.date.issued1973
dc.description.abstractThe reaction between H atoms and hydrogen sulphide, with and without added nitric oxide, has been studied by following the H atom, S atom and SH radical concentrations with time using electron spin resonance detection. The results are fully explained by the mechanism (1)–(4) H + H2S→H2+ SH, k1= 5.0 × 108 l. mol–1 s–1(1), H + SH → H2+ S, k2= 2.5 × 1010 l. mol–1 s–1(2), SH + NO → stable species, k3= 6.3 × 108 l. mol–1 s–1(3), SH + SH → H2S + S, k4= 7.8 × 109 l. mol–1 s–1. (4) with no evidence for significant surface effects (the walls were coated with boric acid). The results demonstrate conclusively that reaction (2) is very important in this system and that previous measurements of k1 which neglect this reaction may require correction.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/17504
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2)en_US
dc.subjectChemistryen_US
dc.subjectElectron Spin Resonanceen_US
dc.subjectHydrogen Atomsen_US
dc.subjectHydrogen Sulphideen_US
dc.subjectRadical Reactionsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleElectron Spin Resonance Study of the Reaction of Hydrogen Atoms with Hydrogen Sulphideen_US
dc.typeArticleen_US

Files

Collections

Journal Articles (before-1995)