Rate of Combination of Trimethylsilyl Radicals in the Gas Phase

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dc.contributor.authorCadman, P.
dc.contributor.authorTilsley, G. M.
dc.contributor.authorTrotman-Dickenson, A. F.
dc.date.accessioned2025-01-31T05:59:03Z
dc.date.available2025-01-31T05:59:03Z
dc.date.issued1972
dc.description.abstractTrimcthylsilyl radicals have been generated by the mercury photosensitized decomposition of trimcthylsilane. The absolute rate of combination of these radicals has been measured by the classical rotating sector technique between 317 and 399 K, using the abstraction of chlorine from ethyl chloride to give chlorotrimcthylsilane as the pilot reaction. The activation energy for combination was found to be negligible and the rate coefficient to be given by: log (K/ml mol~l s-1) = 14.25±0.30 where the error is estimated from the experimental scatter.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16956
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10)en_US
dc.subjectChemistryen_US
dc.subjectTrimethylsilyl Radicalsen_US
dc.subjectMercury Photosensitizeden_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleRate of Combination of Trimethylsilyl Radicals in the Gas Phaseen_US
dc.typeArticleen_US

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