Reducing-Agent-Free Convergent Synthesis of Hydroxyimino-Decorated Tetracyclic Fused Cinnolines via RhIII-Catalyzed Annulation Using Nitroolefins
| dc.contributor.author | Sakhuja, Rajeev | |
| dc.date.accessioned | 2021-11-11T10:57:56Z | |
| dc.date.available | 2021-11-11T10:57:56Z | |
| dc.date.issued | 2021-01 | |
| dc.description.abstract | A mild Rh-catalyzed method was developed for the synthesis of hydroxyimino functionalized indazolo[1,2-a]cinnolines and phthalazino[2,3-a]cinnolines by reductive [4 + 2] annulation between 1-arylindazolones and 2-aryl-2,3-dihydrophthalazine-1,4-diones with varied nitroolefins. The targeted oxime decorated tetracyclic fused cinnolines were synthesized via sequential C–H activation/olefin insertion/reduction under reducing-agent-free conditions. | en_US |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.joc.0c02729 | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3342 | |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Annulations | en_US |
| dc.subject | H2 Purification | en_US |
| dc.subject | Organic compounds | en_US |
| dc.subject | Column chromatography | en_US |
| dc.subject | Ethanol | en_US |
| dc.title | Reducing-Agent-Free Convergent Synthesis of Hydroxyimino-Decorated Tetracyclic Fused Cinnolines via RhIII-Catalyzed Annulation Using Nitroolefins | en_US |
| dc.type | Article | en_US |
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