Phosphotungstic acid on silica with modified acid sites as a solid catalyst for selective cleavage of tert-butyldimethylsilyl ethers

dc.contributor.authorKumar, Indresh
dc.date.accessioned2021-10-27T04:13:53Z
dc.date.available2021-10-27T04:13:53Z
dc.date.issued2008-05-15
dc.description.abstractThe strength and nature of acid sites of bulk phosphotungstic acid could be modified after dispersing it on silica support which was characterized by XRD, ammonia TPD and 31P MAS NMR techniques. This solid acid catalyst was found to be highly selective for the cleavage of tert-butyldimethylsilyl ethers at room temperature. The catalyst was easily recovered by filtration and could be reused for several times without loss of any activity giving a TON of 9.5 × 105.en_US
dc.identifier.urihttps://www.sciencedirect.com/science/article/abs/pii/S1566736708000885?via%3Dihub
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2994
dc.language.isoenen_US
dc.publisherElsieveren_US
dc.subjectChemistryen_US
dc.subjectSolid aciden_US
dc.subjectAmmonia TPDen_US
dc.subjectXRDen_US
dc.subjectCatalytic cleavageen_US
dc.titlePhosphotungstic acid on silica with modified acid sites as a solid catalyst for selective cleavage of tert-butyldimethylsilyl ethersen_US
dc.typeArticleen_US

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