Electrochemical Oxidative Coupling Between Benzylic C(sp3)–H and N–H of Secondary Amines: Rapid Synthesis of α-Amino α-Aryl Esters
| dc.contributor.author | Kumar, Indresh | |
| dc.date.accessioned | 2024-09-12T09:34:36Z | |
| dc.date.available | 2024-09-12T09:34:36Z | |
| dc.date.issued | 2021-06 | |
| dc.description.abstract | An intermolecular electrochemical coupling between the benzylic C(sp3)–H bond and various secondary amines is reported. The electronic behavior of two electronically rich units viz the α-position of α-aryl acetates and amines was engineered electrochemically, thus facilitating their reactivity for the direct access of α-amino esters. A series of acyclic/cyclic secondary amines and α-aryl acetates were tested to furnish the corresponding α-amino esters with high yields (up to 92%) under mild conditions. | en_US |
| dc.identifier.uri | https://pubs.acs.org/doi/full/10.1021/acs.joc.1c00944 | |
| dc.identifier.uri | https://dspace.bits-pilani.ac.in/xmlui/handle/123456789/15552 | |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Amines | en_US |
| dc.subject | Fossil fuels | en_US |
| dc.subject | Organic compounds | en_US |
| dc.subject | Purification | en_US |
| dc.title | Electrochemical Oxidative Coupling Between Benzylic C(sp3)–H and N–H of Secondary Amines: Rapid Synthesis of α-Amino α-Aryl Esters | en_US |
| dc.type | Article | en_US |
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