Kinetics of the reaction of the nickel(II) ion with pyridine-2-azo-p-dimethylaniline in t-butanol + water mixtures

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dc.contributor.authorCaldin, Edward F.
dc.contributor.authorGodfrey, Peter
dc.date.accessioned2025-02-19T11:50:52Z
dc.date.available2025-02-19T11:50:52Z
dc.date.issued1974
dc.description.abstractRate constants and activation parameters have been determined for the reaction of the nickel(II) ion with pyridine -2-azo-p-dimethylaniline, in a series of t-butanol + water mixtures with mole fractions from 0 to 0.4 t-butanol. The rate constant at 25°C varies little with composition, but the enthalpy and entropy of activation both vary considerably, with compensation; they show maxima and minima, which are discussed in relation to theories of solvent structure.en_US
dc.identifier.urihttps://dspace.bits-pilani.ac.in/handle/123456789/17914
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12)en_US
dc.subjectChemistryen_US
dc.subjectReactionsen_US
dc.subjectKineticsen_US
dc.subjectNickel Ionen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleKinetics of the reaction of the nickel(II) ion with pyridine-2-azo-p-dimethylaniline in t-butanol + water mixturesen_US
dc.typeArticleen_US

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