Rhodium-catalyzed regioselective c7ar-functionalization of tryptophan with quinones and its late stage peptide exemplification

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dc.contributor.authorSakhuja, Rajeev
dc.date.accessioned2025-07-30T06:31:13Z
dc.date.available2025-07-30T06:31:13Z
dc.date.issued2023-11
dc.description.abstractPivaloyl-directed Rh(III)-catalyzed regioselective C7Ar-H functionalization of protected tryptophans were accomplished with 1,4-benzoquinones, furnishing a series of quinone-appended tryptophan-based unnatural amino acids in high yields. Further, the late stage functionalization on tryptophan-containing dipeptides was achieved with 1,4-benzoquinones in moderate reactivity.en_US
dc.identifier.urihttps://aces.onlinelibrary.wiley.com/doi/full/10.1002/ajoc.202300503
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19110
dc.language.isoenen_US
dc.publisherWileyen_US
dc.subjectChemistryen_US
dc.subjectPivaloyl-directed Rh(III) catalysisen_US
dc.subjectC7‑Ar‑H functionalization of tryptophanen_US
dc.subjectQuinone-appended tryptophan derivativesen_US
dc.titleRhodium-catalyzed regioselective c7ar-functionalization of tryptophan with quinones and its late stage peptide exemplificationen_US
dc.typeArticleen_US

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