Synthesis and characterization of cis and trans isomers of [NiL2(NCS)2] [L=1-(2-aminoethyl)pyrrolidine]: X-ray single-crystal structures
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Date
2000-07-30
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Elsiever
Abstract
The isomeric complexes trans-[NiL2(NCS)2] (violet) (1) and cis-[NiL2(NCS)2] (blue) (2) [L=1-(2-aminoethyl)pyrrolidine] have been synthesized, varying solvents and temperature, and their X-ray crystal structures have been determined. Both the isomers possess the same space group, P21/c, having distorted octahedral geometry.
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Keywords
Chemistry, Nickel(II)thiocyanate, 1-(2-Aminoethyl)pyrrolidine, Crystal structures