Thermodynamic Properties of Hydrogen in Palladium and its Alloys under Conditions of Constant Volume

dc.contributor.authorOates, W. Alan
dc.contributor.authorFlanagan, Ted B
dc.date.accessioned2025-11-21T05:43:27Z
dc.date.available2025-11-21T05:43:27Z
dc.date.issued1977
dc.descriptionThermodynamic properties for the solution of hydrogen in palladium and its alloys are experimentally determined under conditions of constant pressure (corresponding to a free surface solid). In this research these data are converted to conditions of constant alloy volume. For palladium/hydrogen it is predicted that the phase change, α→β, which is so characteristic of this system, no longer appears under conditions of constant volume. This is indicative of the fact that long range dipole-dipole elastic interactions predominate in this system. A different sequence of behaviour of ΔµxsH→0 values with atom fraction of substituted metal is predicted for alloys of the type palladium + group IB for constant volume conditions as compared with conditions of constant pressure.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20158
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07)en_US
dc.subjectChemistryen_US
dc.subjectThermodynamic propertiesen_US
dc.subjectPalladiumen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleThermodynamic Properties of Hydrogen in Palladium and its Alloys under Conditions of Constant Volumeen_US
dc.typeArticleen_US

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