Electron Spin Resonance Detection of Radical Intermediates During Photo-oxidation by Metal Ions in Solution

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dc.contributor.authorGreatorex, David
dc.contributor.authorHill, Richard J.
dc.contributor.authorKemp, Terence J.
dc.contributor.authorStone, Thomas J.
dc.date.accessioned2025-02-17T11:14:52Z
dc.date.available2025-02-17T11:14:52Z
dc.date.issued1974
dc.description.abstractIrradiation of fluid solutions of ceric and uranyl ions in various organic media in the temperature range 140–290 K gives rise in many cases to well-resolved e.s.r. spectra of solvent-derived radicals, enabling characterisation of the photolytic process. Whilst UO2+2 photo-oxidises predominantly, but not exclusively, by means of abstracting a hydrogen atom from carbon adjacent to an activating site such as —OH or —CO2H, Ce(IV) attacks by a process of C—C fission; for example RCO2H yields R˙ and R′CH2OH yields, not R′ĊHOH as is customarily found at 77 K, but R′˙.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17834
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)en_US
dc.subjectChemistryen_US
dc.subjectElectron Spin Resonance Detectionen_US
dc.subjectPhoto-oxidationen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleElectron Spin Resonance Detection of Radical Intermediates During Photo-oxidation by Metal Ions in Solutionen_US
dc.typeArticleen_US

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