Interfacial charge recombination of Os(ii)–polypyridyl–resorcinol complex on oleic acid capped TiO2 surface: what determines the dynamics?

dc.contributor.author	Banerjee, Tanmay
dc.date.accessioned	2021-11-11T11:22:34Z
dc.date.available	2021-11-11T11:22:34Z
dc.date.issued	2013
dc.description.abstract	Femtosecond transient absorption spectroscopic studies of an osmium(II)–polypyridyl–resorcinol complex, 1, on oleic acid capped TiO2 have been carried out and the results have been compared with our previous studies on poly(vinyl)alcohol capped TiO2. While on both these surfaces the complex exhibits a single exponential <120 fs injection, the back electron transfer reaction is slower on the oleic acid capped TiO2 surface early on while it is faster on the same surface at longer times than on poly(vinyl)alcohol capped TiO2. The probable origin of these disparate observations has been analyzed.	en_US
dc.identifier.uri	https://pubs.rsc.org/en/content/articlelanding/2013/nj/c3nj00550j
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3490
dc.language.iso	en	en_US
dc.publisher	RSC	en_US
dc.subject	Chemistry	en_US
dc.subject	Os(ii)–polypyridyl–resorcinol	en_US
dc.title	Interfacial charge recombination of Os(ii)–polypyridyl–resorcinol complex on oleic acid capped TiO2 surface: what determines the dynamics?	en_US
dc.type	Article	en_US

Files

Now showing 1 - 1 of 1