Mechanism of thermolysis of tetramethylsilane and trimethylsilane

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dc.contributor.authorBaldwin, Alan C.
dc.contributor.authorDavidson, Iain M. T.
dc.contributor.authorReed, Michael D.
dc.date.accessioned2025-05-08T10:43:36Z
dc.date.available2025-05-08T10:43:36Z
dc.date.issued1978
dc.description.abstractThe thermolysis of tetramethylsilane has been studied in a pulsed stirred-flow system between 840 and 1055 K, yielding significantly different Arrhenius parameters above and below 950 K. The high temperature results relate to a non-chain mechanism, whence D(Me3Si–Me)= 355 ± 6 kJ mol–1 while the low temperature results relate to a short chain sequence. A mechanism for the latter is shown by computer-aided numerical integration to be consistent with experimental results, as is a similar chain mechanism for the thermolysis of trimethylsilane.en_US
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18889
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)en_US
dc.subjectChemistryen_US
dc.subjectThermolysis of tetramethylsilaneen_US
dc.subjectthermolysis of trimethylsilaneen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleMechanism of thermolysis of tetramethylsilane and trimethylsilaneen_US
dc.typeArticleen_US

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