On the Hydrolysis of Agn, T1H, Sn111 and CuI[1
| dc.contributor.author | Asmus, Klaus-Dieter | |
| dc.contributor.author | Toffel, Peter | |
| dc.contributor.author | Bonifacio, Marija | |
| dc.date.accessioned | 2025-05-06T11:09:34Z | |
| dc.date.available | 2025-05-06T11:09:34Z | |
| dc.date.issued | 1978 | |
| dc.description.abstract | Using pulse radiolysis with optical, conductometric and polarographic detection it is shown that the oxidation of T1+, Ag+, Cu2 ! and Sn2 ■ by hydroxyl radicals proceeds via on OH adduct: Mc"+ + •OH Me(OH)'l+. Depending on pH, the OH adduct may react with a proton followed by water elimination, may add OH- or react with water followed by elimination of a proton. The pA" values for the equilibria Me('l+‘)+ = Mc(OH)n+ ~ Me(OH)O-1)4 decrease with increasing state of oxidation of Me. The oxidative properties decrease with increasing state of hydrolysis. | en_US |
| dc.identifier.uri | https://dspace.bits-pilani.ac.in/handle/123456789/18861 | |
| dc.language.iso | en | en_US |
| dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08) | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Hydrolysis | en_US |
| dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
| dc.title | On the Hydrolysis of Agn, T1H, Sn111 and CuI[1 | en_US |
| dc.type | Article | en_US |