Structural Analysis of Some Molten Materials by X-ray Diffraction Part 5.—LiCl, PbCL and their Mixtures
| dc.contributor.author | Ohno, Hideo | |
| dc.contributor.author | Yoroki, Mitsugu | |
| dc.contributor.author | Furukawa, Kazuo | |
| dc.contributor.author | Takagi, Yoshiki | |
| dc.contributor.author | Nakamura, Tetsuro | |
| dc.date.accessioned | 2025-04-28T09:23:29Z | |
| dc.date.available | 2025-04-28T09:23:29Z | |
| dc.date.issued | 1978 | |
| dc.description.abstract | The molten structure of PbCl2, LiCl and their mixtures were examined by X-ray diffraction analysis. In molten Pbcl2, each Pb atom is surrounded by about eight Cl atoms at a distance of 2.92 Å, which is near to the sum of the ionic radii of Pb2+ and Cl–. It is expected that only very few rigid complex anions will be present in molten PbCl2. The results of X-ray diffraction analysis in molten PbCl2 are consistent with those of Raman spectroscopy. The average Pb–Pb interaction in the molten state should be intermediate between a b.c.c. and an s.c. arrangement and the s.c. arrangement takes precedence with increasing LiCl concentration. | en_US |
| dc.identifier.uri | https://dspace.bits-pilani.ac.in/handle/123456789/18813 | |
| dc.language.iso | en | en_US |
| dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07) | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Structural analysis | en_US |
| dc.subject | Molten materials | en_US |
| dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
| dc.title | Structural Analysis of Some Molten Materials by X-ray Diffraction Part 5.—LiCl, PbCL and their Mixtures | en_US |
| dc.type | Article | en_US |