Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex
| dc.contributor.author | Sah, Ajay Kumar | |
| dc.date.accessioned | 2021-10-14T13:07:50Z | |
| dc.date.available | 2021-10-14T13:07:50Z | |
| dc.date.issued | 2013 | |
| dc.description.abstract | A cyclen-based cryptand (2) was prepared in a two-step synthesis from dioxocyclen. When a Cu(CF3SO3)2 complex with 2 was prepared in methanol, the 2/Cu(CF3SO3)2 complex incorporated one methanol in the cavity formed by the diethyleneoxy unit and the NH group of the cyclen. When prepared in ethanol, the 2/Cu(CF3SO3)2 complex similarly incorporated one ethanol. Cold electrospray ionization mass spectrometry (CSI-MS) of the 2/Cu(CF3SO3)2/alcohol complexes selectively retains methanol over ethanol under CSI-MS conditions. | en_US |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ic4021417 | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2783 | |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Macrocyclic compounds | en_US |
| dc.subject | Ethers | en_US |
| dc.subject | Alcohols | en_US |
| dc.subject | Ethanol | en_US |
| dc.subject | Molecules | en_US |
| dc.title | Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex | en_US |
| dc.type | Article | en_US |
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