One-pot synthesis of strong solid state emitting mono-cyclometalated iridium(iii) complexes: study of their aggregation induced enhanced phosphorescence
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Date
2012
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Publisher
RSC
Abstract
Strong solid-state greenish-blue emitting, mono-cyclometalated iridium complexes, [Ir(ppy)(PPh3)2(H)(Cl)], 2a and [Ir(F2ppy)(PPh3)2(H)(Cl)], 2b [ppyH = 2-phenylpyridine; F2ppyH = 2-(2′,4′-difluoro)phenylpyridine], have been synthesized by a convenient route. The ‘aggregation induced enhanced phosphorescence (AIEP)’ activity exhibited by these complexes has been rationalized.
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Keywords
Chemistry, Synthesis, Emitting mono-cyclometalated iridium(iii), Phosphorescence